Catalytic decomposition of soybean oil in the presence of different zeolites.

被引:16
作者
Santos, FR
Ferreira, JCN
da Costa, SRR
机构
[1] Univ Fed Rural Rio De Janeiro, Inst Ciencias Exatas, Dept Quim, BR-23851970 Seropedica, RJ, Brazil
[2] Univ Fed Rural Rio De Janeiro, Inst Tecnol, Dept Tecnol Quim, BR-23851970 Seropedica, RJ, Brazil
来源
QUIMICA NOVA | 1998年 / 21卷 / 05期
关键词
soybean oil; zeolites; amorphous silica-alumina;
D O I
10.1590/S0100-40421998000500005
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The catalytic decomposition of soybean oil was studied in a fz bed reactor at 673 anti 773 K and using amorphous silica-alumina and the zeolites USY, H-Mordenite and H-ZSM-5 as catalysts. Both the selectivity and the catalytic activity were determined by studying the product composition resulting from the chemical reactions. Physicochemical characteristics of the catalysts were obtained by X-ray fluorescence, Fourier Transform infrared spectroscopy, Si-29 and Al-27 Nuclear Magnetic Ressonance and textural analysis. The zeolites USY and H-ZSM-5 showing higher Bronsted acidity, yielded products with higher concentration in aromatic hydrocarbons, whereas with both H-Mordenite and amorphous silica-alumina the main products were paraffins.
引用
收藏
页码:560 / 563
页数:4
相关论文
共 17 条
[1]  
CHANG C, 1984, J CATAL, V86, P89
[2]  
CHANG CC, 1942, IND ENG CHEM, V39, P1543
[3]   M2 FORMING - A PROCESS FOR AROMATIZATION OF LIGHT-HYDROCARBONS [J].
CHEN, NY ;
YAN, TY .
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1986, 25 (01) :151-155
[4]   HYDROGEN TRANSFER ON USY ZEOLITES DURING GAS OIL CRACKING - INFLUENCE OF THE ADSORPTION CHARACTERISTICS OF THE ZEOLITE CATALYSTS [J].
CORMA, A ;
FARALDOS, M ;
MARTINEZ, A ;
MIFSUD, A .
JOURNAL OF CATALYSIS, 1990, 122 (02) :230-239
[5]  
DASILVA JG, 1986, THESIS U PARIS 6
[6]  
DASILVA JG, 1989, CATAL TODAY, V5, P533
[7]  
ENGELHARDT G, 1991, INTRO ZEOLITE SCI PR, P285
[8]  
FERNANDES LD, 1992, THESIS COPPE U FEDER
[9]  
FILHO GNR, 1992, J AM OIL CHEM SOC, V69, P265
[10]  
GIANETTO G, 1990, ZEOLITAS CARACTERIST