Reversible 300 K ferromagnetic ordering in a diluted magnetic semiconductor

被引:272
作者
Schwartz, DA [1 ]
Gamelin, DR [1 ]
机构
[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA
关键词
D O I
10.1002/adma.200400456
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reversible 300 K ferromagnetic ordering in a diluted magnetic semiconductor. Co2+:ZnO, is achieved by lattice incorporation and removal of the native n-type defect, interstitial Zn, resulting in "off" and "on" states (Figure. red triangles and blue circles). Spectroscopic and magnetic data implicate a double-exchange mechanism for ferromagnetism. These results suggest new opportunities for integrating, magnetism and conductivity in semiconductor sensor or spin-based electronics devices.
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页码:2115 / +
页数:6
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共 31 条
[1]   CONSIDERATIONS ON DOUBLE EXCHANGE [J].
ANDERSON, PW ;
HASEGAWA, H .
PHYSICAL REVIEW, 1955, 100 (02) :675-681
[2]   ANOMALOUS OPTICAL ABSORPTION LIMIT IN INSB [J].
BURSTEIN, E .
PHYSICAL REVIEW, 1954, 93 (03) :632-633
[3]   New materials for spintronics [J].
Chambers, SA ;
Yoo, YK .
MRS BULLETIN, 2003, 28 (10) :706-708
[4]   Mixed-valence manganites [J].
Coey, JMD ;
Viret, M ;
von Molnár, S .
ADVANCES IN PHYSICS, 1999, 48 (02) :167-293
[5]   EFFECT OF THERMOCHEMICAL REDUCTION ON THE ELECTRICAL, OPTICAL-ABSORPTION, AND POSITRON-ANNIHILATION CHARACTERISTICS OF ZNO CRYSTALS [J].
DELACRUZ, RM ;
PAREJA, R ;
GONZALEZ, R ;
BOATNER, LA ;
CHEN, Y .
PHYSICAL REVIEW B, 1992, 45 (12) :6581-6586
[6]   Zener model description of ferromagnetism in zinc-blende magnetic semiconductors [J].
Dietl, T ;
Ohno, H ;
Matsukura, F ;
Cibert, J ;
Ferrand, D .
SCIENCE, 2000, 287 (5455) :1019-1022
[7]   Dilute magnetic semiconductors - Functional ferromagnets [J].
Dietl, T .
NATURE MATERIALS, 2003, 2 (10) :646-648
[8]   Ferromagnetic semiconductors [J].
Dietl, T .
SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 2002, 17 (04) :377-392
[9]   Excited-state contributions to ground-state properties of mixed-valence dimers: Spectral and electronic-structural studies of [Fe-2(OH)(3)(tmtacn)(2)](2+) related to the [Fe2S2](+) active sites of plant-type ferredoxins [J].
Gamelin, DR ;
Bominaar, EL ;
Kirk, ML ;
Wieghardt, K ;
Solomon, EI .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (34) :8085-8097
[10]   Residual native shallow donor in ZnO [J].
Look, DC ;
Hemsky, JW ;
Sizelove, JR .
PHYSICAL REVIEW LETTERS, 1999, 82 (12) :2552-2555