An experimental study on permeability, diffusivity, and selectivity of CO2 and CH4 through [bmim][PF6] ionic liquid supported on an alumina membrane: Investigation of temperature fluctuations effects

被引：60

作者：

Barghi, S. H. ^{[2
]}

Adibi, M. ^{[1
]}

Rashtchian, D. ^{[2
]}

机构：

[1] Res Inst Petrochem Ind RIPI, Chem & Petrochem Div, Tehran, Iran

[2] Sharif Univ Technol, Dept Chem Engn, Tehran 1136511155, Iran

来源：

JOURNAL OF MEMBRANE SCIENCE | 2010年 / 362卷 / 1-2期

关键词：

Supported ionic liquid; Permeability; Diffusivity; CO2/CH4; separation; CARBON-DIOXIDE; SOLUBILITY; GAS; HEXAFLUOROPHOSPHATE; IMIDAZOLIUM; SILMS;

D O I：

10.1016/j.memsci.2010.06.047

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

In order to define a new temperature correction factor in this study, accurate experimental values were presented for permeability and diffusivity of carbon dioxide and methane in imidazolium-based room temperature ionic liquid [bmim][PF6] (1-butyl-3-methylimidazolium hexafluorophosphate) immobilized on an inorganic membrane support Results were presented as a function of temperature and pressure for temperatures within 300-320 K and pressures below 50 kPa According to the literature, experimental values of permeability and diffusivity for CH4 in [bmim][PF6] vs temperature are reported for the first time in this study. Results obtained for CO2 permeability revealed good agreement with data reported by other researchers (C) 2010 Elsevier B V. All rights reserved

引用

页码：346 / 352

页数：7

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