Molecular recognition in a supramolecular polymer system translated into mechanical motion

被引:31
作者
Schneider, HJ [1 ]
Liu, TJ
Lomadze, N
机构
[1] Univ Saarland, FR Organ Chem, D-66041 Saarbrucken, Germany
[2] Inst Neue Mat, D-66041 Saarbrucken, Germany
关键词
actuators; chemomechanics; molecular recognition; polymers; supramolecular chemistry;
D O I
10.1002/anie.200219965
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Action and reaction: Implementation of molecular recognition centers into flexible elastomers allows selective recognition processes to be translated into fully reversible macroscopic motions for the first time (see scheme). The expansion and contraction of the polymers depends both on the effector binding energy and the pH value.
引用
收藏
页码:3544 / 3546
页数:3
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