The formation of medium-sized rings by the intramolecular cyclization of arylnitrenium ions

被引：12

作者：

Abramovitch, RA ^{[1
]}

Miller, J

de Souza, AJC

机构：

[1] Clemson Univ, Dept Chem, Clemson, SC 29634 USA

[2] Univ Estadual Campinas, BR-13100000 Campinas, SP, Brazil

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 36期

关键词：

nitrenium; intramolecular cyclizations; medium-sized rings; MMX;

D O I：

10.1016/S0040-4039(03)01591-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of an aminodibenzo[a,c]octadiene and an aminodibenzo[a,c]octatriene, guided by molecular mechanics calculations, was effected by the intramolecular cyclization of the corresponding open chain nitrenium ions. Also reported is the predicted failure to synthesize another aminodibenzo[a,c]octadiene using this method. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：6965 / 6967

页数：3

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