An unusual photosensitizer:: Dyad of eosin-tris(2,2′-bipyridine)Ru(II)

被引:9
作者
Jing, BW [1 ]
Zhang, MH [1 ]
Shen, T [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
关键词
D O I
10.1021/ol0353924
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A dyad of eosin and tris(2,2'-bipyridine)Ru(11) was prepared, and its photophysical properties were investigated. The photosensitization of eosin is greatly enhanced by introduction of tris(2,2'-bipyridine)Ru(II), which is verified via photooxygenation of anthracene derivatives. The electron-transfer mechanism of photosensitization is also discussed.
引用
收藏
页码:3709 / 3711
页数:3
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