Nanocelluloses: A New Family of Nature-Based Materials

被引:3446
作者
Klemm, Dieter [1 ,2 ]
Kramer, Friederike [1 ,2 ]
Moritz, Sebastian [1 ,2 ]
Lindstrom, Tom [3 ]
Ankerfors, Mikael [3 ]
Gray, Derek [4 ]
Dorris, Annie [4 ]
机构
[1] Polymet Jena Assoc, D-07745 Jena, Germany
[2] Jenpolymer Mat Ltd & Co KG, D-07745 Jena, Germany
[3] Innventia AB, Mat Proc, S-11486 Stockholm, Sweden
[4] McGill Univ, Dept Chem, Montreal, PQ H3A 2A7, Canada
关键词
cellulose; nanocellulose; nanomaterials; nature-based materials; polymers; CHIRAL NEMATIC SUSPENSIONS; STRAW CELLULOSE WHISKERS; BACTERIAL CELLULOSE; MECHANICAL-PROPERTIES; MICROFIBRILLATED CELLULOSE; ACETOBACTER-XYLINUM; NANOCOMPOSITE MATERIALS; POLYMER NANOCOMPOSITES; POLYELECTROLYTE MULTILAYERS; MICROCRYSTALLINE CELLULOSE;
D O I
10.1002/anie.201001273
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cellulose fibrils with widths in the nanometer range are nature-based materials with unique and potentially useful features. Most importantly, these novel nanocelluloses open up the strongly expanding fields of sustainable materials and nanocomposites, as well as medical and life-science devices, to the natural polymer cellulose. The nanodimensions of the structural elements result in a high surface area and hence the powerful interaction of these celluloses with surrounding species, such as water, organic and polymeric compounds, nanoparticles, and living cells. This Review assembles the current knowledge on the isolation of microfibrillated cellulose from wood and its application in nanocomposites; the preparation of nanocrystalline cellulose and its use as a reinforcing agent; and the biofabrication of bacterial nanocellulose, as well as its evaluation as a biomaterial for medical implants. Cellulose goes nano: Renewed research effort on cellulose has led to nanoscale materials derived from this abundant, renewable, and potentially carbon-neutral source. Microfibrillated cellulose, nanocrystalline cellulose (see polarized microscopy image), and bacterial nanocellulose provide unique product opportunities: gels and foams, structured films of cellulose, and medical implants, respectively. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:5438 / 5466
页数:29
相关论文
共 396 条
[1]   Short natural-fibre reinforced polyethylene and natural rubber composites: Effect of silane coupling agents and fibres loading [J].
Abdelmouleh, M. ;
Boufi, S. ;
Belgacem, M. N. ;
Dufresne, A. .
COMPOSITES SCIENCE AND TECHNOLOGY, 2007, 67 (7-8) :1627-1639
[2]   Obtaining cellulose nanofibers with a uniform width of 15 nm from wood [J].
Abe, Kentaro ;
Iwamoto, Shinichiro ;
Yano, Hiroyuki .
BIOMACROMOLECULES, 2007, 8 (10) :3276-3278
[3]   Cellulose nanofibrils-adsorption with poly(amideamine) epichlorohydrin studied by QCM-D and application as a paper strength additive [J].
Ahola, Susanna ;
Osterberg, Monika ;
Laine, Janne .
CELLULOSE, 2008, 15 (02) :303-314
[4]  
AKIMOTO M, 2008, Patent No. 20080107789
[5]  
ANDRESEN M, 2007, 233 ACS NAT M CHICA, P178
[6]   Water-in-oil emulsions stabilized by hydrophobized microfibrillated cellulose [J].
Andresen, Martin ;
Stenius, Per .
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2007, 28 (06) :837-844
[7]  
Anette HH, 2007, Patent No. [WO2007001229-A1, 2007001229]
[8]   Plasticized starch/tunicin whiskers nanocomposites.: 1.: Structural analysis [J].
Anglès, MN ;
Dufresne, A .
MACROMOLECULES, 2000, 33 (22) :8344-8353
[9]   Plasticized starch/tunicin whiskers nanocomposite materials.: 2.: Mechanical behavior [J].
Anglès, MN ;
Dufresne, A .
MACROMOLECULES, 2001, 34 (09) :2921-2931
[10]  
[Anonymous], 1956, TAPPI