Physical and chemical characterization of poly(2-bromo-5-hexyloxy-p-phenylenevinylene) and poly(5,5′-dibromo-2,2′-bis-hexyloxy-4,4′-biphenylenevinylene) -: comparison to related polymers

被引：18

作者：

Benvenho, ARV

Lessmann, R

Hümmelgen, IA

Mello, RMQ

Li, RWC

Bazito, FFC

Gruber, J

机构：

[1] Univ Fed Parana, Dept Fis, Grupo Disposit Optoelect Organ, BR-81531990 Curitiba, Parana, Brazil

[2] Univ Fed Parana, Dept Quim, BR-81531990 Curitiba, Parana, Brazil

[3] Univ Sao Paulo, Inst Quim, BR-05513970 Sao Paulo, SP, Brazil

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2006年 / 95卷 / 01期

基金：

巴西圣保罗研究基金会;

关键词：

conjugated polymers; biphenylenevinylene derivatives; charge carrier mobilities;

D O I：

10.1016/j.matchemphys.2005.06.022

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We performed the synthesis, spectroscopic and electrical characterization of poly(2-bromo-5-hexyloxy-p-phenylenevinylene), BHPPV, and poly(5,5'-dibromo-2,2'-bis-hexyloxy-4,4'-biphenylenevinylene), BHBPV. We determined the positive charge carrier mobility, similar to 3.7 x 10(-7) cm(2) V-1 S-1 for BHPPV and 5.9 x 10(-7) cm(2) V-1 s(-1) for BHBPV and estimated the energy levels, energy gap and determined the photoluminescence spectrum for both polymers. The results are compared with similar results on poly(p-phenylenevinylene) and poly(biphenylenevinylene) derivatives, discussing trends in physical parameters. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：176 / 182

页数：7

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[1] POLYMER ELECTROLUMINESCENCE IN THE NEAR-INFRARED [J].