Physical and electrical properties of hafnium-zirconium-oxide films grown by atomic layer deposition

被引:36
作者
Bang, Seokhwan [1 ]
Lee, Seungjun [1 ]
Jeon, Sunyeol [1 ]
Kwon, Semyung [1 ]
Jeong, Wooho [1 ]
Kim, Seokhoon [1 ]
Jeon, Hyeongtag [1 ]
机构
[1] Hanyang Univ, Div Mat Sci & Engn, Seoul 133791, South Korea
关键词
D O I
10.1149/1.2945908
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
We deposited HfO2, ZrO2, and ZrxHf1-xO2 films having different ZrO2 contents on Si substrates by atomic layer deposition at 300 degrees C and investigated their physical and electrical characteristics. The HfO2 and ZrO2 films with thicknesses of about 20 nm exhibited crystalline structures composed of monoclinic and tetragonal phases, respectively. As the ZrO2 content in the hafnium-zirconium-oxide was increased, the ratio of the tetragonal phase seen in the crystal increased. These changes in crystal phase led to changes in electrical properties. The crystalline phases and electrical properties of the hafnium-zirconium-oxide films exhibited a strong dependence on their Hf/Zr composition ratio. (C) 2008 The Electrochemical Society.
引用
收藏
页码:H633 / H637
页数:5
相关论文
共 19 条
[1]   Thermodynamics of tetragonal zirconia formation in a nanolaminate film [J].
Aita, CR ;
Wiggins, MD ;
Whig, R ;
Scanlan, CM ;
GajdardziskaJosifovska, M .
JOURNAL OF APPLIED PHYSICS, 1996, 79 (02) :1176-1178
[2]  
[Anonymous], IBM J RES DEV
[3]   High-density layer at the SiO2/Si interface observed by difference x-ray reflectivity [J].
Awaji, N ;
Ohkubo, S ;
Nakanishi, T ;
Sugita, Y ;
Takasaki, K ;
Komiya, S .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 1996, 35 (1B) :L67-L70
[4]  
Bersuker G, 2004, MATER RES SOC SYMP P, V811, P31
[5]   Oxygen diffusion in ultrafine grained monoclinic ZrO2 [J].
Brossmann, U ;
Würschum, R ;
Södervall, U ;
Schaefer, HE .
JOURNAL OF APPLIED PHYSICS, 1999, 85 (11) :7646-7654
[6]   Thermal stability and structural characteristics of HfO2 films on Si (100) grown by atomic-layer deposition [J].
Cho, MH ;
Roh, YS ;
Whang, CN ;
Jeong, K ;
Nahm, SW ;
Ko, DH ;
Lee, JH ;
Lee, NI ;
Fujihara, K .
APPLIED PHYSICS LETTERS, 2002, 81 (03) :472-474
[7]   Hafnium zirconate gate dielectric for advanced gate stack applications [J].
Hegde, R. I. ;
Triyoso, D. H. ;
Samavedam, S. B. ;
White, B. E., Jr. .
JOURNAL OF APPLIED PHYSICS, 2007, 101 (07)
[8]  
Kim H., 2005, J MATER RES, V20, P11
[9]  
Massalski T. B., 1990, BINARY ALLOY PHASE D, V2, P2097
[10]   Band offsets of wide-band-gap oxides and implications for future electronic devices [J].
Robertson, J .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2000, 18 (03) :1785-1791