Post-synthetic modification of isomorphic coordination layers: exchange dynamics of metal ions in a single crystal to single crystal fashion

被引：89

作者：

Mukherjee, Gargi ^{[1
]}

Biradha, Kumar ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 36期

关键词：

ORGANIC FRAMEWORKS; ANION-EXCHANGE; CATION-EXCHANGE; BUILDING UNITS; GUEST EXCHANGE; LIGAND; COMPLEXES; POLYMERS; NETWORKS; TRANSFORMATIONS;

D O I：

10.1039/c2cc30983a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A diverse set of guest molecules template the consistent formation of fifteen iso-structural layered structures containing a pyridine based tripodal ligand, divalent metal ions and anions. These materials have shown a remarkable ability to interconvert from Zn(II) to Cu(II), Cd(II) to Cu(II), Cu(II) to Cd(II) complexes in a SCSC (single crystal-to-single crystal) fashion.

引用

页码：4293 / 4295

页数：3

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