Efficient total syntheses of (±)protolichesterinic acid and (±)rocellaric acid via tungsten-π-allyl complexes

被引：16

作者：

Chen, MJ ^{[1
]}

Liu, RS ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30043, Taiwan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 51期

关键词：

D O I：

10.1016/S0040-4039(98)02146-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Total syntheses of racemic protolichesterinic acid (1) and rocellaric add (2) were achieved with the use of tungsten-pi-allyl complex in the key step. In this synthetic route, compounds 1 and 2 were prepared in four and six steps respectively starting from readily available chloropropargyl derivatives. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：9465 / 9468

页数：4

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[2]

AZIZA J, 1990, TETRAHEDRON LETT, V46, P1931

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