Synthesis, characterization, and photovoltaic properties of a low-bandgap copolymer based on 2,1,3-benzooxadiazole

被引:88
作者
Jiang, Jian-Ming [1 ]
Yang, Po-An [1 ]
Chen, Hsiu-Cheng [1 ]
Wei, Kung-Hwa [1 ]
机构
[1] Natl Chiao Tung Univ, Dept Mat Sci & Engn, Hsihchu, Taiwan
关键词
HETEROJUNCTION SOLAR-CELLS; PHASE-SEPARATION; POLYMER; EFFICIENT; UNITS; CYCLOPENTADITHIOPHENE; MOBILITY; DESIGN;
D O I
10.1039/c1cc12040a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
PBDTBO, a conjugated polymer comprising benzo[1,2-b:4,5-b']dithiophene (BDT) and 5,6-bis(octyloxy) benzo[c][1,2,5]-oxadiazole (BO) units, exhibits a deep HOMO energy level of -5.27 eV and excellent solubility. A device incorporating PBDTBO and [6,6]-phenyl-C-61-butyric acid methyl ester (1 : 1, w/w) exhibited a power conversion efficiency of 5.7%.
引用
收藏
页码:8877 / 8879
页数:3
相关论文
共 35 条
[1]   Efficient Solar Cells Based on an Easily Accessible Diketopyrrolopyrrole Polymer [J].
Bijleveld, Johan C. ;
Gevaerts, Veronique S. ;
Di Nuzzo, Daniele ;
Turbiez, Mathieu ;
Mathijssen, Simon G. J. ;
de Leeuw, Dago M. ;
Wienk, Martijn M. ;
Janssen, Rene A. J. .
ADVANCED MATERIALS, 2010, 22 (35) :E242-+
[2]   Copolymers of Cyclopentadithiophene and Electron-Deficient Aromatic Units Designed for Photovoltaic Applications [J].
Bijleveld, Johan C. ;
Shahid, Munazza ;
Gilot, Jan ;
Wienk, Martijn M. ;
Janssen, Rene A. J. .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (20) :3262-3270
[3]   Toward a rational design of poly(2,7-carbazole) derivatives for solar cells [J].
Blouin, Nicolas ;
Michaud, Alexandre ;
Gendron, David ;
Wakim, Salem ;
Blair, Emily ;
Neagu-Plesu, Rodica ;
Belletete, Michel ;
Durocher, Gilles ;
Tao, Ye ;
Leclerc, Mario .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (02) :732-742
[4]  
Brabec CJ, 2001, ADV FUNCT MATER, V11, P374, DOI 10.1002/1616-3028(200110)11:5<374::AID-ADFM374>3.0.CO
[5]  
2-W
[6]   Intramolecular donor-acceptor regioregular poly(3-hexylthiophene)s presenting octylphenanthrenyl-imidazole moieties exhibit enhanced charge transfer for heterojunction solar cell applications [J].
Chang, Yao-Te ;
Hsu, So-Lin ;
Chen, Guan-Yu ;
Su, Ming-Hsin ;
Singh, Thounaojam Avinash ;
Diau, Eric Wei-Guang ;
Wei, Kung-Hwa .
ADVANCED FUNCTIONAL MATERIALS, 2008, 18 (16) :2356-2365
[7]   Soluble phenanthrenyl-imidazole-presenting regioregular poly (3-octylthiophene) copolymers having tunable bandgaps for solar cell applications [J].
Chang, Yao-Te ;
Hsu, So-Lin ;
Su, Ming-Hsin ;
Wei, Kung-Hwa .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (16) :3326-3331
[8]   Intramolecular Donor-Acceptor Regioregular Poly(hexylphenanthrenyl-imidazole thiophene) Exhibits Enhanced Hole Mobility for Heterojunction Solar Cell Applications [J].
Chang, Yao-Te ;
Hsu, So-Lin ;
Su, Ming-Hsin ;
Wei, Kung-Hwa .
ADVANCED MATERIALS, 2009, 21 (20) :2093-2097
[9]   Crystalline conjugated polymer containing fused 2,5-di(thiophen-2-yl)thieno[2,3-b]thiophene and thieno[3,4-c]pyrrole-4,6-dione units for bulk heterojunction solar cells [J].
Chen, Guan-Yu ;
Cheng, Yu-Hsin ;
Chou, Yi-Jen ;
Su, Ming-Shin ;
Chen, Chia-Min ;
Wei, Kung-Hwa .
CHEMICAL COMMUNICATIONS, 2011, 47 (17) :5064-5066
[10]   Synthesis and Characterization of a Narrow-Bandgap Polymer Containing Alternating Cyclopentadithiophene and Diketo-Pyrrolo-Pyrrole Units for Solar Cell Applications [J].
Chen, Guan-Yu ;
Chiang, Chien-Ming ;
Kekuda, Dhananjay ;
Lan, Shang-Che ;
Chu, Chih-Wei ;
Wei, Kung-Hwa .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2010, 48 (07) :1669-1675