Selective complexation of disaccharides by a novel D-2-symmetrical receptor in protic solvent mixtures

被引：57

作者：

Neidlein, U ^{[1
]}

Diederich, F ^{[1
]}

机构：

[1] ETH ZURICH,ORGAN CHEM LAB,CH-8092 ZURICH,SWITZERLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 13期

关键词：

D O I：

10.1039/cc9960001493

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of an optically active, 1,1'-binaphthyl-derived cyclophane receptor with a preorganized central cavity lined with four anionic phosphodiester groups for ionic hydrogen bonding is described. In competitive protic solvent mixtures, this receptor forms stable 1:1 complexes with disaccharides whereas the smaller monosaccharides are not significantly bound.

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收藏

页码：1493 / 1494

页数：2

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