A versatile precursor for the synthesis of new ruthenium olefin metathesis catalysts

被引：366

作者：

Sanford, MS ^{[1
]}

Love, JA ^{[1
]}

Grubbs, RH ^{[1
]}

机构：

[1] CALTECH, Div Chem & Chem Engn, Arnold & Mabel Beckman Labs Chem Synth, Pasadena, CA 91125 USA

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 25期

关键词：

D O I：

10.1021/om010599r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ruthenium complex (IMesH(2))(Cl)(2)(C5H5N)(2)Ru=CHPh [IMesH(2) = 1,3-dimesityl-4,5-dihydroimidazol-2-ylidenel (3) was prepared by the reaction of (IMesH(2))(PCy3)(Cl)(2)Ru=CHPh (2) with an excess of pyridine. Complex 3 contains substitutionally labile pyridine and chloride ligands and serves as a versatile starting material for the synthesis of new ruthenium benzylidenes.

引用

页码：5314 / 5318

页数：5

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