Elucidating the intercalation mechanism of zinc ions into α-MnO2 for rechargeable zinc batteries

被引：648

作者：

Lee, Boeun ^{[1
]}

Lee, Hae Ri ^{[1
]}

Kim, Haesik ^{[1
]}

Chung, Kyung Yoon ^{[1
]}

Cho, Byung Won ^{[1
]}

Oh, Si Hyoung ^{[1
]}

机构：

[1] Korea Inst Sci & Technol, Seoul 136791, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 45期

关键词：

CRYSTAL-STRUCTURE; MANGANESE OXIDES; TODOROKITE; CATHODE; BIRNESSITE; CHALCOPHANITE; BUSERITE; MNO2;

D O I：

10.1039/c5cc02585k

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

The intercalation mechanism of zinc ions into 2 x 2 tunnels of an alpha-MnO2 cathode for rechargeable zinc batteries was revealed. It involves a series of single and two-phase reaction steps and produces buserite, a layered compound with an interlayer spacing of 11 angstrom as a discharge product.

引用

收藏

页码：9265 / 9268

页数：4

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