Observations on the versatility of methylenecyclopropanes as olefinic components in the intramolecular Pauson-Khand reaction

被引：29

作者：

Corlay, H

Fouquet, E

Magnier, E

Motherwell, WB ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[2] Univ London Univ Coll, Christopher Ingold Labs, Dept Chem, London WC1H 0AJ, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 02期

关键词：

D O I：

10.1039/a807333c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclopropyl tethered methylenecyclopropanes can function in the intramolecular Pauson-Khand reaction either as simple alkene components, or give rearranged hydroindenones in which neither of the two carbon atoms of the alkyne component form part of the cyclopentenone unit in the product.

引用

页码：183 / 184

页数：2

共 25 条

[1]

BAPUJI SA, 1989, TETRAHEDRON LETT, V30, P7107

[2]

BINGER P, 1987, TOP CURR CHEM, V135, P77

[3] Versatile synthesis of enantiomerically pure 2-alkoxy-1-ethynylcyclopropanes and their application in the synthesis of enantiomerically pure bicyclo-[3.3.0]oct-1-en-3-ones [J].