Hyperthermal Ar atom scattering from a C(0001) surface

被引:32
作者
Gibson, K. D. [1 ,2 ]
Sibener, S. J. [1 ,2 ]
Upadhyaya, Hari P. [3 ]
Brunsvold, Amy L. [3 ]
Zhang, Jianming [3 ]
Minton, Timothy K. [3 ]
Troya, Diego [4 ]
机构
[1] Univ Chicago, James Franck Inst, Chicago, IL 60637 USA
[2] Univ Chicago, Dept Chem, Chicago, IL 60637 USA
[3] Montana State Univ, Dept Chem & Biochem, Bozeman, MT 59717 USA
[4] Virginia Tech, Dept Chem, Blacksburg, VA 24061 USA
关键词
D O I
10.1063/1.2924126
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Experiments and simulations on the scattering of hyperthermal Ar from a C(0001) surface have been conducted. Measurements of the energy and angular distributions of the scattered Ar flux were made over a range of incident angles, incident energies (2.8-14.1 eV), and surface temperatures (150-700 K). In all cases, the scattering is concentrated in a narrow superspecular peak, with significant energy exchange with the surface. The simulations closely reproduce the experimental observations. Unlike recent experiments on hyperthermal Xe scattering from graphite [Watanabe , Eur. Phys. J. D 38, 103 (2006)], the angular dependence of the energy loss is not approximated by the hard cubes model. The simulations are used to investigate why parallel momentum conservation describes Xe scattering, but not Ar scattering, from the surface of graphite. These studies extend our knowledge of gas-surface collisional energy transfer in the hyperthermal regime, and also demonstrate the importance of performing realistic numerical simulations for modeling such encounters. (c) 2008 American Institute of Physics.
引用
收藏
页数:7
相关论文
共 21 条
[1]   ATOM SURFACE SCATTERING DYNAMICS AT HYPERTHERMAL ENERGIES [J].
AMIRAV, A ;
CARDILLO, MJ ;
TREVOR, PL ;
LIM, C ;
TULLY, JC .
JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (03) :1796-1807
[2]   Ar scattering on Ru (0001): a comparison to the washboard model [J].
Berenbak, B ;
Zboray, S ;
Riedmuller, B ;
Papageorgopoulos, DC ;
Stolte, S ;
Kleyn, AW .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2002, 4 (01) :68-74
[3]   STUDY OF GAS-GRAPHITE POTENTIAL BY MEANS OF HELIUM ATOM DIFFRACTION [J].
BOATO, G ;
CANTINI, P ;
TATAREK, R .
PHYSICAL REVIEW LETTERS, 1978, 40 (13) :887-889
[4]   A second-generation reactive empirical bond order (REBO) potential energy expression for hydrocarbons [J].
Brenner, DW ;
Shenderova, OA ;
Harrison, JA ;
Stuart, SJ ;
Ni, B ;
Sinnott, SB .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2002, 14 (04) :783-802
[5]   A HIGH-FLUX SOURCE OF ENERGETIC OXYGEN-ATOMS FOR MATERIAL DEGRADATION STUDIES [J].
CALEDONIA, GE ;
KRECH, RH ;
GREEN, BD .
AIAA JOURNAL, 1987, 25 (01) :59-63
[6]   Scattering of xenon from Ni(111): Collision-induced corrugation and energy transfer dynamics [J].
Ellison, MD ;
Matthews, CM ;
Zare, RN .
JOURNAL OF CHEMICAL PHYSICS, 2000, 112 (04) :1975-1983
[7]  
*EPAPS, 2002, EJCPSA6128022821 EPA
[8]   On non-binary nature of the collisions of heavy hyperthermal particles with solid surfaces [J].
Ferleger, VK ;
Wojciechowski, IA .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2000, 164 (164) :641-644
[9]  
GOODMAN FO, 1976, DYNAMICS GAS SURFACE
[10]   Energy exchange in structure scattering:: a molecular dynamics study for Cs+ from Pt(111) [J].
Lahaye, RJWE ;
Kang, H .
SURFACE SCIENCE, 2001, 490 (03) :327-335