Hydrogen-bonding ionophores for inorganic anions and nucleotides and their application in chemical sensors

被引：17

作者：

Bühlmann, P

Amemiya, S

Nishizawa, S

Xiao, KP

Umezawa, Y

机构：

[1] Univ Tokyo, Sch Sci, Dept Chem, Tokyo 1130033, Japan

[2] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan

来源：

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1998年 / 32卷 / 2-3期

关键词：

ion-selective electrode; optode; voltammetric sensor; hydrogen bond; thiourea; nucleotide; anion;

D O I：

10.1023/A:1008055225528

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The potential and limits of hydrogen-bonding ionophores and their use in chemical sensors are discussed. Several hydrogen-bonding bis-thiourea ionophores have been found to complex inorganic anions, among them most strongly H2PO4-. Using such ionophores, ion-selective electrodes for chloride and sulfate have been developed. Furthermore, hosts that bind nucleotides with up to five hydrogen bonds have been synthesized. They have been applied in nucleotide selective electrodes, optodes and voltammetric sensors mimicking ion channels.

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收藏

页码：151 / 163

页数：13

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