Self-consistent Ornstein-Zernike approximation for lattice gases

被引:54
作者
Dickman, R [1 ]
Stell, G [1 ]
机构
[1] SUNY STONY BROOK,DEPT CHEM,STONY BROOK,NY 11790
关键词
D O I
10.1103/PhysRevLett.77.996
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
A self-consistent approximation for the structure factor of three-dimensional lattice gases yields remarkably accurate predictions (less than 3% error over most of the temperature range) for the correlation length, isothermal compressibility, specific heat, and the coexistence curve. Critical temperatures agree to within 0.2%, and other critical properties to within (1-2)%, of the best numerical estimates. Until temperature and density are within 1% of their critical values, the approximate effective critical exponents do not differ appreciably from their estimated exact form; they attain their limiting spherical-model values only much closer to critical. The method should prove useful for a variety of three-dimensional lattice-gas and fluid problems; it is inappropriate to two dimensions, where it predicts criticality at zero temperature.
引用
收藏
页码:996 / 999
页数:4
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