New nickel catalysts supported on highly porous alumina intercalated laponite for methane reforming with CO2

被引:67
作者
Hwang, KS
Zhu, HY [1 ]
Lu, GQ
机构
[1] Univ Queensland, Dept Chem Engn, St Lucia, Qld 4072, Australia
[2] ChungCheong Coll, Dept Environm Chem, Cheongju 363792, South Korea
基金
澳大利亚研究理事会;
关键词
CO2; reforming; nickel catalyst; intercalated clay; surfactant template;
D O I
10.1016/S0920-5861(01)00299-1
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Alumina intercalated laponite (Al-laponite) was prepared with a polyethylene oxide (PEO) surfactant and used as supports of nickel catalysts for the carbon dioxide reforming reaction with methane to synthesis gas. The effects of the supports of intercalated laponite and catalyst preparation on catalytic activity, stability and carbon deposition were investigated for the above reforming reaction. We found that the pore structure of the Al-laponite supports can be tailored with the surfactant and the catalyst with well-developed porosity exhibited higher catalytic activity and a longer time of catalyst stability. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:183 / 190
页数:8
相关论文
共 19 条
[1]  
Burch R., 1988, CATALYSIS TODAY, V2
[2]   Effects of promoters and preparation procedures on reforming of methane with carbon dioxide over Ni/Al2O3 catalyst [J].
Cheng, ZX ;
Wu, QL ;
Li, JL ;
Zhu, QM .
CATALYSIS TODAY, 1996, 30 (1-3) :147-155
[3]  
EDWARDS JH, 1994, NATURAL GAS CONVERSI, V2, P291
[4]  
GADALLA AM, 1988, CHEM ENG SCI, V42, P3042
[5]   Non-aggressive pillaring of clays with zirconium acetate.: Comparison with alumina pillared clays [J].
Gandía, LM ;
Toranzo, R ;
Vicente, MA ;
Gil, A .
APPLIED CATALYSIS A-GENERAL, 1999, 183 (01) :23-33
[6]  
GREGG SJ, 1982, ADSORPTION SURFACE
[7]  
Li WY, 1995, COAL SCI TECHNOL, V24, P727
[8]   CATALYTIC CRACKING WITH AN INTERLAYERED CLAY - A TWO-DIMENSIONAL MOLECULAR-SIEVE [J].
OCCELLI, ML .
INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1983, 22 (04) :553-559
[9]   Preparation and properties of two-dimensional microporous pillared interlayered solids [J].
Ohtsuka, K .
CHEMISTRY OF MATERIALS, 1997, 9 (10) :2039-2050
[10]   INTERCALATED CLAY CATALYSTS [J].
PINNAVAIA, TJ .
SCIENCE, 1983, 220 (4595) :365-371