Electrochemistry of quaternary ammonium binaphthyl salts

被引：3

作者：

Abbott, AP ^{[1
]}

Cheung, CSM

Lonergan, GR

Stará, IG

Stary, I

Kocovsky, P

机构：

[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

[2] AVCR, Inst Organ Chem & Biochem, Prague 16610 6, Czech Republic

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 07期

关键词：

D O I：

10.1039/a900386j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The redox behaviour of the binaphthyl unit in quaternary ammonium salts with an appended crown ether (3) is dramatically affected by the presence of metal cations and this effect can be used as an analytical tool to detect micromolar concentrations of alkali metal ions.

引用

页码：641 / 642

页数：2

共 18 条

[11]

Noyori R., 1994, ASYMMETRIC CATALYSIS

[12]

ROSINI C, 1992, SYNTHESIS-STUTTGART, P503

[13] Electron transfer reactions of radical cation and anion of (R)-(-)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate in aqueous solution. A pulse radiolysis study [J].

Shoute, LCT .

JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (30) :5535-5542

[14] Axially chiral 1,1'-binaphthyls with non-identical groups in 2,2'-positions. Synthesis of the enantiomerically pure 2-hydroxy-2'-thiol and substituted 2-amino-2'-thiols [J].

Smrcina, M ;

Vyskocil, S ;

Polivkova, J ;

Polakova, J ;

Sejbal, J ;

Hanus, V ;

Polasek, M ;

Verrier, H ;

Kocovsky, P .

TETRAHEDRON-ASYMMETRY, 1997, 8 (04) :537-546

[15] SYNTHESIS OF ENANTIOMERICALLY PURE 2,2'-DIHYDROXY-1,1'-BINAPHTHYL, 2,2'-DIAMINO-1,1'-BINAPHTHYL, AND 2-AMINO-2'-HYDROXY-1,1'-BINAPHTHYL - COMPARISON OF PROCESSES OPERATING AS DIASTEREOSELECTIVE CRYSTALLIZATION AND AS 2ND-ORDER ASYMMETRIC TRANSFORMATION [J].

SMRCINA, M ;

LORENC, M ;

HANUS, V ;

SEDMERA, P ;

KOCOVSKY, P .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (06) :1917-1920

[16]

SMRCINA M, 1993, J ORG CHEM, V58, P4543

[17] NUCLEOPHILIC CLEAVAGE OF 4,5-DIHYDRO-3H-DINAPHTH[2,1-C-1',2'-E]AZEPINIUM QUATERNARY-SALTS - A CONVENIENT APPROACH TO NEW AXIALLY DISSYMMETRIC AND AXIALLY ASYMMETRIC LIGANDS [J].

STARA, IG ;

STARY, I ;

ZAVADA, J .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (25) :6966-6969

[18] CATION RECOGNITION PROPERTIES OF POLYPYRROLE 3-SUBSTITUTED BY AZACROWN ETHERS [J].

YOUSSOUFI, HK ;

HMYENE, M ;

GARNIER, F ;

DELABOUGLISE, D .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (20) :1550-1552

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