Synthesis of ferrocene substituted pyrrolidine derivatives via Et2Zn catalyzed 1,3-dipolar cycloaddition reactions of azomethine ylides

被引：10

作者：

Dogan, Ö ^{[1
]}

Koyuncu, H ^{[1
]}

机构：

[1] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 631卷 / 1-2期

关键词：

ferrocene; pyrrolidine; diethylzinc catalysis; 1,3-dipolar cycloadditions;

D O I：

10.1016/S0022-328X(01)01034-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis of ferrocene substituted pyrrolidine derivatives via diethylzinc catalyzed 1,3-dipolar cycloadditions of azomethine ylides is described. Azomethine ylides were generated from glycine methyl ester and ferrocenecarboxaldehyde by the 'imine tautomerization' method and trapped with dipolarophiles to give the corresponding cycloadducts in reasonable yields and high regio- and stereoselectivity. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

收藏

页码：135 / 138

页数：4

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