Synthesis of 3,4-bis[(methoxycarbonyl)methyl]thiophene and bis-, ter- and and pentathiophenes with alternating 3,4-bis[(methoxycarbonyl)methyl]-substituted rings

被引：41

作者：

Fazio, A ^{[1
]}

Gabriele, B

Salerno, G

Destri, S

机构：

[1] Univ Calabria, Dipartimento Chim, I-87030 Arcavacata, Cosenza, Italy

[2] CNR, Ist Chim Macromol, I-20133 Milan, Italy

来源：

TETRAHEDRON | 1999年 / 55卷 / 02期

关键词：

carbonylation; coupling reactions; palladium; thiophenes;

D O I：

10.1016/S0040-4020(98)01047-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of 3,4-bis[(methoxycarbonyl)methyl]thiophene and bis-, ter- and pentathiophenes, with alternating 3,4-bis(methoxycarbonyl)methyl-substituted rings, is reported, These new thiophene derivatives are possible precursors for the preparation of new conducting polymers useful as materials for electronics. (C) 1998 Elsevier Science Ltd. All rights reserved.

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收藏

页码：485 / 502

页数：18

相关论文

共 32 条

[1] ELECTROLUMINESCENCE FROM SUBSTITUTED POLY(THIOPHENES) - FROM BLUE TO NEAR-INFRARED [J].

ANDERSSON, MR ;

BERGGREN, M ;

INGANAS, O ;

GUSTAFSSON, G ;

GUSTAFSSONCARLBERG, JC ;

SELSE, D ;

HJERTBERG, T ;

WENNERSTROM, O .

MACROMOLECULES, 1995, 28 (22) :7525-7529

[2] Palladium-catalysed sequential carboxylation-alkoxycarbonylation of acetylenic amines [J].

Bacchi, A ;

Chiusoli, GP ;

Costa, M ;

Gabriele, B ;

Righi, C ;

Salerno, G .

CHEMICAL COMMUNICATIONS, 1997, (13) :1209-1210

[3] Nitrogen heterocycles by palladium-catalysed oxidative cyclization-alkoxycarbonylation of acetylenic ureas [J].

Bacchi, A ;

Chiusoli, GP ;

Costa, M ;

Sani, C ;

Gabriele, B ;

Salerno, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 562 (01) :35-43

[4]

BOJORNHOLM T, 1996, ADV MAT, V8, P920

[5] VERSATILE SYNTHESIS OF BETA-LACTAMS, GAMMA-LACTAMS OR OXAZOLINES BY PALLADIUM-CATALYSED OXIDATIVE CARBONYLATION OF 1-SUBSTITUTED PROP-2-YNYLAMINES [J].

BONARDI, A ;

COSTA, M ;

GABRIELE, B ;

SALERNO, G ;

CHIUSOLI, GP .

TETRAHEDRON LETTERS, 1995, 36 (41) :7495-7498

[6]

BOUNAN MM, 1995, ADV MAT, V7, P385

[7]

CAGNIANT P, 1986, THIOPHENE ITS DERI 2, V44, P119

[8] REGIOCONTROLLED SYNTHESIS OF POLY(3-ALKYLTHIOPHENES) MEDIATED BY RIEKE ZINC - THEIR CHARACTERIZATION AND SOLID-STATE PROPERTIES [J].

CHEN, TA ;

WU, XM ;

RIEKE, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (01) :233-244

[9]

CHIUSOLI GP, 1985, GAZZ CHIM ITAL, V115, P691

[10]

CHIUSOLI GP, 1989, SYNTHESIS-STUTTGART, P262

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