Conjugate addition of arylsilanes to unsaturated carbonyl compounds catalyzed by rhodium in air and water

被引：70

作者：

Huang, TS ^{[1
]}

Li, CJ ^{[1
]}

机构：

[1] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 22期

关键词：

D O I：

10.1039/b106768k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

ArSiCl3 and Ar2SiCl2, believed to be unstable in aqueous media, reacted efficiently with alpha,beta -unsaturated ketones and esters in air and water (in the presence of sodium fluoride and a rhodium catalyst), giving good to excellent yields of the desired conjugate addition products.

引用

页码：2348 / 2349

页数：2

共 30 条

[1]

AMICE P, 1976, SYNTHESIS-STUTTGART, P196

[2]

ESHELBY JJ, 1993, SYNLETT, P279

[3]

FLEMMING S, 1995, SYNTHESIS-STUTTGART, P317

[4]

FRY JL, 1990, ORG SYNTH COLLECT, V7, P393