Recent advances in the chemistry of N5+N5- and high-oxygen compounds

被引：144

作者：

Christe, Karl O. ^{[1
]}

机构：

[1] Univ So Calif, Loker Res Inst, Los Angeles, CA 90089 USA

来源：

PROPELLANTS EXPLOSIVES PYROTECHNICS | 2007年 / 32卷 / 03期

关键词：

polynitrogen; high-nitrogen compounds; hgh-oxygen carriers; oxidizer balanced ionic liquids; liquid monopropellants;

D O I：

10.1002/prep.200700020

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An overview of our work in the areas of polynitrogen and high-nitrogen and high-oxygen chemistry is given. Areas of interest include the synthesis and characterization of novel polynitrogen ions, such as N-5(+) and N-5(-). Efforts are discussed to combine the N-5(+) cation with energetic counter-ions, such as N-3(-), NO3-, ClO4-, B(N-3)(4)(-) and P(N-3)(6)-. In the area of high-oxygen carriers, complex nitrato anions were successfully combined with tetrazolium cations to yield CO/H2O balanced ionic liquids of interest for liquid monopropellants.

引用

页码：194 / 204

页数：11

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