Micro-probe Raman spectroscopy for detection of inhomogeneities in YVO4 single crystals

被引：25

作者：

Erdei, S ^{[1
]}

Jin, B ^{[1
]}

Ainger, FW ^{[1
]}

Bhalla, AS ^{[1
]}

Keszei, B ^{[1
]}

Vandlik, J ^{[1
]}

Suveges, A ^{[1
]}

机构：

[1] HUNGARIAN ACAD SCI,RES INST MAT SCI,BUDAPEST,HUNGARY

来源：

JOURNAL OF APPLIED PHYSICS | 1996年 / 79卷 / 06期

关键词：

D O I：

10.1063/1.361276

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Several near quasicongruent undoped YVO4 single crystals grown by the Czochralski (CZ) technique as well as near stoichiometric YVO4 single crystals grown by the top-seeded solution growth technique, were investigated by micro-probe Raman spectroscopy using unpolarized argon-ion laser light. The line broadening effects of the Raman active mode at 379 cm(-1) indicate that all CZ grown crystals posses wider peak widths than near stoichiometric YVO4. In the latter case a value of 9.23 cm(-1) was measured for full width at half-maximum. Although the annealing process in O-2 can improve the oxygen stoichiometry int he originally slightly oxygen deficient CZ grown YVO4 crystals, certain remaining peak broadening effects demonstrate a Y-V related stoichiometry problem by both lower (external) and higher frequency (internal) modes. Radial inhomogeneous distributions were observed in CZ specimens by the shift of external Raman modes at 157 and 162 cm(-1) frequencies. In addition, nonassigned low intensity extra Raman peaks appeared over 1000 cm(-1) frequencies in all CZ grown samples. The above detected changes in Y-V-O stoichiometry demonstrate a complex phase system around the homogeneity region of quasicongruent YVO4 specimens and enable a more realistic and unified interpretation of the segregated defects and stoichiometry changes in CZ grown YVO4 single crystals than previously available. (C) 1996 American Institutes of Physics.

引用

页码：2834 / 2838

页数：5

共 22 条

[1]

Bloss F.D., 1971, Crystallography and Crystal Chemistry

[2] GROWTH AND CHARACTERIZATION OF PURE AND RARE-EARTH SUBSTITUTED YVO4 [J].