Hydrotalcite-type materials as catalysts for the synthesis of dimethyl carbonate from ethylene carbonate and methanol

被引：107

作者：

Watanabe, Y ^{[1
]}

Tatsumi, T ^{[1
]}

机构：

[1] Univ Tokyo, Engn Res Inst, Sch Engn, Tokyo 113, Japan

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 1998年 / 22卷 / 1-3期

关键词：

hydrotalcite-type materials; base catalysis; dimethyl carbonate; ester exchange reaction;

D O I：

10.1016/S1387-1811(98)00099-7

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Dimethyl carbonate can be synthesized from ethylene carbonate and methanol by using hydrotalcite-type materials as base catalysts. Especially, Mg-Al hydrotalcite-type materials with low Al concentration in brucite-like layers and high OH- proportion in the intercalated anions give high yield of dimethyl carbonate. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：399 / 407

页数：9

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