Multicompartment micelles formed by self-assembly of linear ABC triblock copolymers in aqueous medium

被引:280
作者
Kubowicz, S
Baussard, JF
Lutz, JF
Thünemann, AF
von Berlepsch, H
Laschewsky, A
机构
[1] Fraunhofer Inst Appl Polymer Res, D-14476 Potsdam, Germany
[2] Max Planck Inst Colloids & Interfaces, D-14476 Potsdam, Germany
[3] Univ Catholique Louvain, Dept Chem, B-1348 Louvain, Belgium
[4] Fed Inst Mat Res & Testing, D-12489 Berlin, Germany
[5] Free Univ Berlin, Res Ctr Electron Microscopy, D-14195 Berlin, Germany
[6] Univ Potsdam, Dept Chem, D-14476 Potsdam, Germany
关键词
amphiphiles; block copolymers; colloids; micelles; self-assembly;
D O I
10.1002/anie.200500584
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) Like a doughnut with a raspberry filling: ABC triblock copolymers, composed of a hydrophilic block with morpholinium units (blue in the picture), a hydrophobic hydrocarbon block (red), and a hydrophobic fluorocarbon-rich block (black), self-assemble in water to form multicompartment micelles with a hydrophilic corona and a hydrophobic core with nanometer-scale subdomains. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5262 / 5265
页数:4
相关论文
共 36 条
[1]   POLYMER-POLYMER PHASE-BEHAVIOR [J].
BATES, FS .
SCIENCE, 1991, 251 (4996) :898-905
[2]   Associative properties of perfluorooctyl end-functionalized polystyrene-poly(ethylene oxide) diblock copolymers [J].
Boschet, F ;
Branger, C ;
Margaillan, A ;
Hogen-Esch, TE .
POLYMER INTERNATIONAL, 2005, 54 (01) :90-95
[3]   ABCA tetrablock copolymer vesicles [J].
Brannan, AK ;
Bates, FS .
MACROMOLECULES, 2004, 37 (24) :8816-8819
[4]   Spheres on spheres - a novel spherical multiphase morphology in polystyrene-block-polybutadiene-block-poly(methyl methacrylate) triblock copolymers [J].
Breiner, U ;
Krappe, U ;
Jakob, T ;
Abetz, V ;
Stadler, R .
POLYMER BULLETIN, 1998, 40 (2-3) :219-226
[5]   A Zwitterionic ABC triblock copolymer that forms a "Trinity" of micellar aggregates in aqueous solution [J].
Cai, YL ;
Armes, SP .
MACROMOLECULES, 2004, 37 (19) :7116-7122
[6]   1998 E.W.R. Steacie Award Lecture Asymmetric amphiphilic block copolymers in solution: a morphological wonderland [J].
Cameron, NS ;
Corbierre, MK ;
Eisenberg, A .
CANADIAN JOURNAL OF CHEMISTRY, 1999, 77 (08) :1311-1326
[7]   EFFECT OF BLOCK SIZE AND SEQUENCE ON THE MICELLIZATION OF ABC TRIBLOCK METHACRYLIC POLYAMPHOLYTES [J].
CHEN, WY ;
ALEXANDRIDIS, P ;
SU, CK ;
PATRICKIOS, CS ;
HERTLER, WR ;
HATTON, TA .
MACROMOLECULES, 1995, 28 (25) :8604-8611
[8]   Polymer vesicles [J].
Discher, DE ;
Eisenberg, A .
SCIENCE, 2002, 297 (5583) :967-973
[9]  
F??rster S., 2002, ANGEW CHEM, V114, P712, DOI DOI 10.1002/1521-3757(20020301)114:5<LESSTHAN>712::AID-ANGE712<GREATERTHAN>3.0.CO
[10]  
2-V