Densities of water plus diethanolamine plus methanol and water plus N-methyldiethanolamine methanol at temperatures ranging from (283.15 to 353.15) K

被引:28
作者
Amararene, F
Balz, P
Bouallou, C
Cadours, R
Lecomte, F
Mougin, P
Richon, D
机构
[1] Ecole Natl Super Mines, CENERG, TEP, F-77305 Fontainebleau, France
[2] Inst Francais Petr, F-92852 Rueil Malmaison, France
关键词
D O I
10.1021/je034094e
中图分类号
O414.1 [热力学];
学科分类号
摘要
Two vibrating tube densimeters have been used to measure the densities of two mixtures-water + diethanolamine + methanol and water + N-methyldiethanolamine + methanol-in the temperature range (283 to 353) K. The alkanolamines and methanol contents are respectively (between 20 and 50 and between 20 and 60) mass %. The experimental results have been correlated using the Redlich- Kister equation for the excess volume. A set of parameters for the Redlich-Kister equation has been determined using the densities of pure compounds and of binary systems available in the literature. The methodology has been extended to density calculations dealing with hybrid solvents.
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页码:1565 / 1570
页数:6
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