Aerobic catalytic epoxidation of unfunctionalized olefins using a new (salen) manganese(III) complex bearing a sesquiterpene Salicylaldehyde derivative

被引：27

作者：

Fernandez, I ^{[1
]}

Pedro, JR ^{[1
]}

delaSalud, R ^{[1
]}

机构：

[1] UNIV VALENCIA,FAC QUIM,DEPT QUIM ORGAN,E-46100 BURJASSOT,VALENCIA,SPAIN

来源：

TETRAHEDRON | 1996年 / 52卷 / 36期

关键词：

D O I：

10.1016/0040-4020(96)00697-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A chiral (salen) manganese (III) complex 1 bearing a sesquiterpene salicylaldehyde and (RP)-1,2-clohexanediamine moieties has been prepared. This complex catalyses the epoxidation of unfunctionalized olefins with iodosylbenzene and molecular oxygen/pivalaldehyde as terminal oxidants. In all cases the chemical yield was high although the enantiomeric excess obtained were low. Copyright (C) 1996 Elsevier Science Ltd.

引用

页码：12031 / 12038

页数：8

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