Aromaticity of phosphorus heterocycles

被引:340
作者
Nyulászi, L [1 ]
机构
[1] Budapest Univ Technol & Econ, Dept Inorgan Chem, H-1521 Budapest, Hungary
关键词
D O I
10.1021/cr990321x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The aromaticity of heterocycles-containing phosphorus in different conditions was studied. The chemical reactivity, in relation to the aromatic stabilization, was also discussed. The pyrrole- and pyridine-type nitrogen allows the formation of cyclic electron delocalization in a large variety of aromatic systems. The results showed that the overall stability of some of the phosphaaromatics is much lower than that of the carbon-containing systems.
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页码:1229 / 1246
页数:18
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