A High-Performance Gas-Separation Membrane Containing Submicrometer-Sized Metal-Organic Framework Crystals

被引：583

作者：

Bae, Tae-Hyun ^{[1
]}

Lee, Jong Suk ^{[1
]}

Qiu, Wulin ^{[1
]}

Koros, William J. ^{[1
]}

Jones, Christopher W. ^{[1
]}

Nair, Sankar ^{[1
]}

机构：

[1] Georgia Inst Technol, Sch Chem & Biomol Engn, Atlanta, GA 30332 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 51期

关键词：

CO2; capture; gas separation; membranes; metal-organic frameworks; zeolites; MIXED-MATRIX MEMBRANES; ZEOLITIC IMIDAZOLATE FRAMEWORKS; CARBON-DIOXIDE CAPTURE; SELECTIVE FLAKES; PERMEABILITY; POLYMERS;

D O I：

10.1002/anie.201006141

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Well matched: Submicrometer-sized metal-organic framework (MOF) crystals (ZIF-90) were synthesized by a nonsolvent-induced crystallization technique and incorporated in mixed-matrix gas-separation membranes. ZIF-90/6FDA-DAM membranes (empty pink circle; beyond the upper bound for polymer membranes) show unprecedented high performance for CO2/CH4 separation by a MOF-based membrane. The key is the combination of the highly selective MOF and a highly permeable polymer. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9863 / 9866

页数：4

共 39 条

[1] Metal organic framework mixed matrix membranes for gas separations [J].

Adams, Ryan ;

Carson, Cantwell ;

Ward, Jason ;

Tannenbaum, Rina ;

Koros, William .

MICROPOROUS AND MESOPOROUS MATERIALS, 2010, 131 (1-3) :13-20

[2] Facile High-Yield Solvothermal Deposition of Inorganic Nanostructures on Zeolite Crystals for Mixed Matrix Membrane Fabrication [J].

Bae, Tae-Hyun ;

Liu, Junqiang ;

Lee, Jong Suk ;

Koros, William J. ;

Jones, Christopher W. ;

Nair, Sankar .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (41) :14662-+

[3] High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture [J].

Banerjee, Rahul ;

Phan, Anh ;

Wang, Bo ;

Knobler, Carolyn ;

Furukawa, Hiroyasu ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2008, 319 (5865) :939-943

[4]

Barbari L. T. A., 1989, J MEMBRANE SCI, V42, P69

[5] Zeolitic Imidazolate Framework Membrane with Molecular Sieving Properties by Microwave-Assisted Solvothermal Synthesis [J].

Bux, Helge ;

Liang, Fangyi ;

Li, Yanshuo ;

Cravillon, Janosch ;

Wiebcke, Michael ;

Caro, Juergen .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (44) :16000-+

[6] Hybrid membrane materials with different metal-organic frameworks (MOFs) for gas separation [J].

Car, Anja ;

Stropnik, Chrtomir ;

Peinemann, Klaus-Viktor .

DESALINATION, 2006, 200 (1-3) :424-426

[7] Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources [J].

Choi, Sunho ;

Drese, Jeffrey H. ;

Jones, Christopher W. .

CHEMSUSCHEM, 2009, 2 (09) :796-854

[8] Mixed matrix membranes (MMMs) comprising organic polymers with dispersed inorganic fillers for gas separation [J].

Chung, Tai-Shung ;

Jiang, Lan Ying ;

Li, Yi ;

Kulprathipanja, Santi .

PROGRESS IN POLYMER SCIENCE, 2007, 32 (04) :483-507

[9] Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework [J].

Cravillon, Janosch ;

Muenzer, Simon ;

Lohmeier, Sven-Jare ;

Feldhoff, Armin ;

Huber, Klaus ;

Wiebcke, Michael .

CHEMISTRY OF MATERIALS, 2009, 21 (08) :1410-1412

[10] MEMBRANES CONTAINING SELECTIVE FLAKES [J].

CUSSLER, EL .

JOURNAL OF MEMBRANE SCIENCE, 1990, 52 (03) :275-288

← 1 2 3 4 →