Stereoisomerism in polyoxometalates: structural and spectroscopic studies of bis(malate)-functionalized cluster systems

被引：108

作者：

Fang, XK ^{[1
]}

Anderson, TM ^{[1
]}

Hou, Y ^{[1
]}

Hill, CL ^{[1
]}

机构：

[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 40期

关键词：

D O I：

10.1039/b508468g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pure enantiomers of a polytungstate cluster [(alpha-P2W16O59)Zr-2(mu 3-O)(mal)](2)(18-) (mal = malate) have been obtained and their conversion to meso diastereomers was observed by P-31 NMR.

引用

页码：5044 / 5046

页数：3

共 24 条

[1] OPTICAL RESOLUTION OF A HETEROPOLYMOLYBDATE ANION
AMA, T
HIDAKA, J
SHIMURA, Y
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1970, 43 (08) : 2654 - +
[2] [Anonymous], 1993, HDB ENANTIOSELECTIVE
[3] *BRUK AXS INC, 2002, SHELXTL VERS 6 12
[4] ELIEL EL, 1994, STEREOCHEMISTRY OGAN
[5] Enantiomerically pure polytungstates: Chirality transfer through zirconium coordination centers to nanosized inorganic clusters
Fang, XK
Anderson, TM
Hill, CL
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (23) : 3540 - 3544
[6] Reporting and evaluating absolute-structure and absolute-configuration determinations
Flack, HD
Bernardinelli, G
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2000, 33 : 1143 - 1148
[7] ON ENANTIOMORPH-POLARITY ESTIMATION
FLACK, HD
[J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV): : 876 - 881
[8] CHIRALITY OF OXIDIZED AND REDUCED OCTADECAMOLYBDODIPHOSPHATE ANIONS - OBSERVATION OF A PFEIFFER EFFECT
GARVEY, JF
POPE, MT
[J]. INORGANIC CHEMISTRY, 1978, 17 (05) : 1115 - 1118
[9] Polyoxometal cations within polyoxometalate anions.: Seven-coordinate uranium and zirconium heteroatom groups in [(UO2)12(μ3-O)4(μ2-H2O)12(P2W15O56)4]32- and [Zr4(μ3-O)2(μ2-OH)2(H2O)4 (P2W16O59)2]14-
Gaunt, AJ
May, I
Collison, D
Holman, KT
Pope, MT
[J]. JOURNAL OF MOLECULAR STRUCTURE, 2003, 656 (1-3) : 101 - 106
[10] Introduction: Polyoxometalates - Multicomponent molecular vehicles to probe fundamental issues and practical problems
Hill, CL
[J]. CHEMICAL REVIEWS, 1998, 98 (01) : 1 - 2

← 1 2 3 →