Characterization of chlorine-, amine- and acrylate-functionalized TEMPO-capped and Bis-TEMPO-capped polystyrenes using MALDI-TOF MS

被引：16

作者：

Bartsch, A ^{[1
]}

Dempwolf, W ^{[1
]}

Bothe, M ^{[1
]}

Flakus, S ^{[1
]}

Schmidt-Naake, G ^{[1
]}

机构：

[1] Tech Univ Clausthal, Inst Tech Chem, D-38678 Clausthal Zellerfeld, Germany

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2003年 / 24卷 / 10期

关键词：

acrylate; amine; halogenated; MALDI; polystyrene; MASS-SPECTROMETRY; MATRIX; INITIATORS;

D O I：

10.1002/marc.200350003

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Chlorine-functionalized TEMPO-capped polystyrenes were investigated using the matrix-assisted laser desorption/ionization time-of-flight (MALDI-TOF) technique. Amine- and acrylate-functionalized agents and bifunctional TEMPO-capped polystyrene were also analyzed to demonstrate the applicability of this method. Using this technique allowed to analyze the conversion of the chlorine function to an acrylate function, which was previously difficult to detect with other methods.

引用

页码：614 / 619

页数：6

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