Vanadium(V) oxytrinitrate, VO(NO3)3.: A powerful reagent for the nitration of aromatic compounds at room temperature under nonacidic conditions

被引：47

作者：

Dove, MFA ^{[1
]}

Manz, B ^{[1
]}

Montgomery, J ^{[1
]}

Pattenden, G ^{[1
]}

Wood, SA ^{[1
]}

机构：

[1] Univ Nottingham, Dept Chem, Nottingham NG7 2RD, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 10期

关键词：

D O I：

10.1039/a801771i

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Vanadium(v) oxytrinitrate is an easy to handle reagent which can be used to nitrate a range of substituted aromatic compounds in dichloromethane at room temperature, leading to >99% yields of nitration products in most cases.

引用

页码：1589 / 1590

页数：2

共 14 条

[1] Direct nitration of pyridine and substituted pyridines [J].

Arnestad, B ;

Bakke, JM ;

Hegbom, I ;

Ranes, E .

ACTA CHEMICA SCANDINAVICA, 1996, 50 (06) :556-557

[2] NITRATION OF AROMATIC AND HETEROAROMATIC-COMPOUNDS BY DINITROGEN PENTAOXIDE [J].

BAKKE, JM ;

HEGBOM, I ;

OVREEIDE, E ;

AABY, K .

ACTA CHEMICA SCANDINAVICA, 1994, 48 (12) :1001-1006

[3] NITRATIONS AND OXIDATIONS WITH INORGANIC NITRATE SALTS IN TRIFLUOROACETIC-ANHYDRIDE [J].

CRIVELLO, JV .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (15) :3056-3060

[4]

FREEMANTLE M, 1996, CHEM ENG NEWS, P7

[5] NITROGEN (V) OXIDE - NITROGEN PENTOXIDE, DINITROGEN PENTOXIDE, NITRIC ANHYDRIDE [J].

GRUENHUT, NS ;

GOLDFRANK, M ;

CUSHING, ML ;

CAESAR, GV .

INORGANIC SYNTHESES, 1950, 3 :78-81

[6]

MORI T, 1995, SYNLETT, P383

[7]

Olah G. A., 1979, ALDRICHIM ACTA, V12, P43

[8]

OLAH GA, 1990, NITRATION METHODS ME

[9] DIE CHEMIE DER ANORGANISCHEN ACYLNITRATE (EIN PROBLEM DES NITRYLCHLORIDS) UND ACYLPERCHLORATE (EIN PROBLEM DES DICHLORHEXOXYDS) [J].

SCHMEISSER, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1955, 67 (17-8) :493-501

[10] Superior methodology for the nitration of simple aromatic compounds [J].

Smith, K ;

Musson, A ;

DeBoos, GA .

CHEMICAL COMMUNICATIONS, 1996, (04) :469-470

← 1 2 →