Novel stereoselective synthesis of 1,3-dienylsilanes via hydromagnesiation reaction of alkynylsilanes

被引：26

作者：

Cai, MZ ^{[1
]}

Hao, WY

Zhao, H

Song, CS

机构：

[1] Jiangxi Normal Univ, Dept Chem, Nanchang 330027, Peoples R China

[2] Shangrao Teachers Coll, Dept Chem, Shangrao 334000, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 679卷 / 01期

基金：

中国国家自然科学基金;

关键词：

alkynylsilane; hydromagnesiation; 1,3-dienylsilane; cross-coupling reaction; stercoselective synthesis;

D O I：

10.1016/S0022-328X(03)00461-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydromagnesiation of alkynylsilanes gives (Z)-alpha-silylvinyl Grignard reagents, which undergo palladium-catalyzed cross-coupling reactions with alkenyl halides to afford stereoselectively 1,3-dienylsilanes in good yields. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：14 / 16

页数：3

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