Poly(butylene succinate) and its copolymers: Research, development and industrialization

被引:604
作者
Xu, Jun [1 ]
Guo, Bao-Hua [1 ]
机构
[1] Tsinghua Univ, Dept Chem Engn, Inst Polymer Sci & Engn, Beijing 100084, Peoples R China
基金
中国国家自然科学基金;
关键词
Biopolymers; Biodegradable polymer; Copolymerization; Industrialization; Poly(butylene succinate) (PBS); BIODEGRADABLE ALIPHATIC POLYESTERS; ENZYMATIC DEGRADATION; ACTINOBACILLUS-SUCCINOGENES; CRYSTALLIZATION BEHAVIOR; MECHANICAL-PROPERTIES; ANAEROBIOSPIRILLUM-SUCCINICIPRODUCENS; PHOSPHOENOLPYRUVATE CARBOXYKINASE; POLY(TETRAMETHYLENE SUCCINATE); DIRECT POLYESTERIFICATION; PHYSICAL-PROPERTIES;
D O I
10.1002/biot.201000136
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Poly(butylene succinate) (PBS) and its copolymers are a family of biodegradable polymers with excellent biodegradability, thermoplastic processability and balanced mechanical properties. In this article, production of the monomers succinic acid and butanediol, synthesis, processing and properties of PBS and its copolymers are reviewed. The physical properties and biodegradation rate of PBS materials can be varied in a wide range through copolymerization with different types and various contents of monomers. PBS has a wide temperature window for thermoplastic processing, which makes the resin suitable for extrusion, injection molding, thermoforming and film blowing. Finally, we summarized industrialization and applications of PBS.
引用
收藏
页码:1149 / 1163
页数:15
相关论文
共 102 条
[1]  
Bhatia A, 2007, KOREA-AUST RHEOL J, V19, P125
[2]   Synthesis and comparative biodegradability studies of three poly(alkylene succinate)s [J].
Bikiaris, DN ;
Papageorgiou, GZ ;
Achilias, DS .
POLYMER DEGRADATION AND STABILITY, 2006, 91 (01) :31-43
[3]   Studies on syntheses and physical properties of biodegradable aliphatic poly(butylene succinate-co-ethylene succinate)s and poly(butylene succinate-co-diethylene glycol succinate)s [J].
Cao, A ;
Okamura, T ;
Nakayama, K ;
Inoue, Y ;
Masuda, T .
POLYMER DEGRADATION AND STABILITY, 2002, 78 (01) :107-117
[4]   Polymerization [J].
Carothers, WH .
CHEMICAL REVIEWS, 1931, 8 (03) :353-426
[5]   Effect of methyl substitution of the ethylene unit on the physical properties of poly(butylene succinate) [J].
Chae, HG ;
Park, SH ;
Kim, BC ;
Kim, DK .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2004, 42 (09) :1759-1766
[6]   Synthesis and characterization of poly(butylene succinate) and its copolyesters containing minor amounts of propylene succinate [J].
Chen, Chi-He ;
Peng, Jyun-Siang ;
Chen, Ming ;
Lu, Hsin-Ying ;
Tsai, Chia-Jung ;
Yang, Chao-Sen .
COLLOID AND POLYMER SCIENCE, 2010, 288 (07) :731-738
[7]  
COOPER JS, 2001, EPA600R01101, P51
[8]   Feasibility of production methods for succinic acid derivatives: a marriage of renewable resources and chemical technology [J].
Cukalovic, Ana ;
Stevens, Christian V. .
BIOFUELS BIOPRODUCTS & BIOREFINING-BIOFPR, 2008, 2 (06) :505-529
[9]  
DAVYMCKEE, 1980, Patent No. 18164
[10]  
De Munck N.A., 1980, GAS PHASE HYDROFORMY