Regulatory parameters of self-healing alginate hydrogel networks prepared via mussel-inspired dynamic chemistry

被引:38
作者
Alegre-Requena, Juan V. [1 ,2 ]
Haering, Marleen [1 ]
Herrera, Raquel P. [2 ]
Diaz Diaz, David [1 ,3 ]
机构
[1] Univ Regensburg, Inst Organ Chem, Univ Str 31, D-93040 Regensburg, Germany
[2] Univ Zaragoza, CSIC, Lab Organocatalisis Asimetr, Dept Quim Organ,ISQCH, Pedro Cerbuna 12, E-50009 Zaragoza, Spain
[3] CSIC, IQAC, Jordi Girona 18-26, ES-08034 Barcelona, Spain
关键词
CROSS-LINKING; ADHESIVE PROTEIN; MYTILUS-EDULIS; COORDINATION CHEMISTRY; BIOMIMETIC ADHESIVES; COATINGS; DOPA; FILMS; COMPLEXES; PEPTIDE;
D O I
10.1039/c6nj02367c
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
Several key parameters that influence both the self-healing properties and water retention capacity of biohydrogel networks made of alginate-dopamine (Alg-DA) conjugates have been studied. A judicious combination of biopolymer concentration, dopamine content, pH-dependent cross-linking of catechol groups and the Fe3+-coordination of the networks allowed control over the self-healing ability of these bioinspired materials. Moreover, the thixotropic nature of model hydrogels was confirmed using oscillatory rheological loop tests.
引用
收藏
页码:8493 / 8501
页数:9
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