A preliminary study of room temperature direct ethyl formate fuel cells for consumer electronic applications

被引:7
作者
Chen, KY [1 ]
Tseung, ACC [1 ]
机构
[1] Univ Greenwich, Sch Chem & Life Sci, London SE18 6PF, England
来源
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1998年 / 451卷 / 1-2期
基金
英国工程与自然科学研究理事会;
关键词
ethyl formate; room temperature fuel cell; poisoning; permselective membrane;
D O I
10.1016/S0022-0728(98)00002-3
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
There is an increasing interest in the development of room temperature fuel cells for consumer electronic applications. Ethyl formate is an ideal fuel-more reactive than methanol and relatively harmless. An attempt to construct an ethyl formate room temperature fuel cell is described. Though the half cell performance of both the Pt/WO3 anode and the Pt/C cathode give encouraging results, the poisoning of the cathode by ethyl formate led to a very low full cell performance. It is concluded that unless efficient permselective membranes are developed, room temperature dissolved fuel fuel cells are not practical. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:1 / 4
页数:4
相关论文
共 8 条
[1]   ANODIC-OXIDATION OF FORMIC-ACID ON ELECTRODEPOSITED PT/WO3 ELECTRODE AT ROOM-TEMPERATURE [J].
CHEN, KY ;
SHEN, PK ;
TSEUNG, ACC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (04) :L54-L56
[2]   OXYGEN REDUCTION ON A ROTATING PT DISC ELECTRODE IN FORMIC ACID-CONTAINING SOLUTIONS [J].
LIU, YR ;
SHEN, PK ;
CHEN, KY ;
TSEUNG, ACC .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1995, 91 (17) :2817-2821
[3]   THE KINETICS OF THE ACID-CATALYSED HYDROLYSIS OF ALKYL FORMATES [J].
SALOMAA, P .
ACTA CHEMICA SCANDINAVICA, 1960, 14 (03) :577-585
[4]   PERFORMANCE OF CO-ELECTRODEPOSITED PT-RU/WO3 ELECTRODES FOR THE ELECTROOXIDATION OF FORMIC-ACID AT ROOM-TEMPERATURE [J].
SHEN, PK ;
CHEN, KY ;
TSEUNG, ACC .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 389 (1-2) :223-225
[5]   ANODIC-OXIDATION OF METHANOL ON PT/WO3 IN ACIDIC MEDIA [J].
SHEN, PK ;
TSEUNG, ACC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (11) :3082-3090
[6]  
TARASEVICH MR, 1973, ELEKTROKHIMIYA, V9, P599
[7]  
Tseung A. C. C., 1972, J APPL ELECTROCHEM, V3, P211
[8]  
TSEUNG ACC, 1995, Patent No. 5470673