Reversible oxygenation of a μ-acetato-di(μ-phenoxo)dicobalt(II) core complex and crystal structure of its oxygenated complex

被引：9

作者：

Furutachi, H ^{[1
]}

Fujinami, S

Suzuki, M

Okawa, H

机构：

[1] Kanazawa Univ, Fac Sci, Dept Chem, Kanazawa, Ishikawa 9201192, Japan

[2] Kyushu Univ, Fac Sci, Dept Chem, Higashi Ku, Fukuoka 8128581, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 08期

关键词：

D O I：

10.1246/cl.1998.779

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mu-acetato-di(mu-phenoxo)dicobalt(II) core complex of the dinucleating macrocycle, derived from the [2:1:1] condensation of 2,6-diformyl-4-methylphenol, ethylenediamine and diethylenetriamine, forms a mu-peroxo complex whose structure is determined by X-ray crystallography.

引用

页码：779 / 780

页数：2

共 14 条

[1]

AUDEEF A, 1976, INORG CHEM, V15, P1432

[2] STRUCTURAL ASPECTS OF SYNTHETIC OXYGEN-CARRIER NN'-ETHYLENEBIS-(SALICYLIDENEIMINATO)COBALT(2) - STRUCTURE OF ADDITION COMPOUND WITH OXYGEN CONTAINING DIMETHYLFORMAMIDE [J].

CALLIGARIS, M ;

NARDIN, G ;

RANDACCIO, L ;

RIPAMONTI, A .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (07) :1069-+

[3] STRUCTURE OF 1 - 2 ADDUCT OF OXYGEN WITH NN'-ETHYLENE-BIS(SALICYLALDEHYDEIMINATO)COBALT(2) CONTAINING DIMETHYLFORMAMIDE [J].

CALLIGARIS, M ;

NARDIN, G ;

RANDACCI.L .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (13) :763-+

[4] HIGH-SPIN BEHAVIOR AND CHEMICAL PROPERTIES OF ORGANOMETALLIC DERIVATIVES OF IRON(III) [J].

FLORIANI, C ;

CALDERAZ.F .

COORDINATION CHEMISTRY REVIEWS, 1972, 8 (1-2) :57-&

[5] Dioxygen oxidation of coordinated nitrosyl to nitro on dmf-bridged dinuclear CoPb complex [J].

Furutachi, H ;

Okawa, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1998, 71 (03) :671-677

[6] (mu-phenoxo)(2)Co(II)M(II) (M=Mn, Fe, Co) core complexes having a ''Co(salen)'' entity embedded in a macrocyclic framework: Synthesis, structure, and properties [J].

Furutachi, H ;

Okawa, H .

INORGANIC CHEMISTRY, 1997, 36 (18) :3911-3918

[7]

JONES RD, 1979, CHEM REV, V79, P137

[8] THERMODYNAMICS OF OXYGEN BINDING IN NATURAL AND SYNTHETIC DIOXYGEN COMPLEXES [J].

NIEDERHOFFER, EC ;

TIMMONS, JH ;

MARTELL, AE .

CHEMICAL REVIEWS, 1984, 84 (02) :137-203

[9] HETERODINUCLEAR NI(II)M(II) (M=PB, MN, FE, CO, NI, CU, ZN) COMPLEXES OF A PHENOL-BASED DINUCLEATING MACROCYCLE WITH DISSIMILAR 4-COORDINATION AND 5-COORDINATION SITES [J].

NISHIO, J ;

OKAWA, H ;

OHTSUKA, S ;

TOMONO, M .

INORGANICA CHIMICA ACTA, 1994, 218 (1-2) :27-32

[10] HETERODINUCLEAR CUIIPBII AND CUIIMII (M = MN, FE, CO, NI, CU, ZN) COMPLEXES OF MACROCYCLES WITH DISSIMILAR 4-COORDINATION AND 5-COORDINATION SITES - SYNTHESIS, STRUCTURES, AND PROPERTIES [J].

OKAWA, H ;

NISHIO, J ;

OHBA, M ;

TADOKORO, M ;

MATSUMOTO, N ;

KOIKAWA, M ;

KIDA, S ;

FENTON, DE .

INORGANIC CHEMISTRY, 1993, 32 (13) :2949-2957

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