Hydrothermal synthesis and structural determination of a three-dimensional microporous iron(III)phosphate:: [H3N(CH2)4NH3]3[Fe8(HPO4)12(PO4)2(H2O)6]

被引：8

作者：

Korzenski, MB ^{[1
]}

Schimek, GL ^{[1
]}

Kolis, JW ^{[1
]}

机构：

[1] Clemson Univ, Dept Chem, Clemson, SC 29634 USA

来源：

EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY | 1998年 / 35卷 / 02期

关键词：

D O I：

10.1016/S0992-4361(98)80193-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new microporous iron(III) phosphate, [H3N(CH2)(4)NH3](3-)[Fe-8(HPO4)(12)(PO4)(2)(H2O)(6)] has been prepared using low temperature hydrothermal methods and characterized by single-crystal X-ray diffraction, EDAX, infrared spectroscopy, thermogravimetric analysis and bond valence sums. The title compound crystallizes as light pink hexagonal-shaped tabs in the centrosymmetric hexagonal space group <P(3)over bar> (No.147) with a = b = 13.495(2) Angstrom, c = 9.396(2) Angstrom, V = 1481.9(4) Angstrom(3) and Z = 4 with R/R-w = 0.044/0.048. The compound exhibits a complicated three-dimensional microporous structure with quaternary ammonium ions acting as a template for the framework. It is similar to previously reported [HN(CH2CH2)(3)NH](3)[Fe-8(HPO4)(12)(PO4)(2)(H2O)(6)].

引用

页码：143 / 160

页数：18

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