Synthesis and characterization of a manganese(III) complex with a new unsymmetrical chelating ligand

被引：9

作者：

Inamoto, K ^{[1
]}

Koikawa, M ^{[1
]}

Nakashima, M ^{[1
]}

Tokii, T ^{[1
]}

机构：

[1] SAGA UNIV, FAC SCI & ENGN, DEPT CHEM, HONJO, SAGA 840, JAPAN

来源：

INORGANICA CHIMICA ACTA | 1996年 / 249卷 / 02期

关键词：

unsymmetrical ligand; crystal structures; manganese(III) complexes; oxazoline complexes; chelate complexes;

D O I：

10.1016/0020-1693(96)05100-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new unsymmetrical chelating ligand of 4,6-dimethyl-3-(4,4-dimethyl-2-oxazolinyl)-N-(2-hydroxy-1,1-dimethylethyl)salicylamide (H(3)LOx) and the mononuclear manganese(III) complex, [Mn(OAc)(H(2)LOx)(2)] (1), have been synthesized and characterized by X-ray structural analyses, elemental analyses and cyclic voltammograms. The crystal structure analyses have revealed that the H(3)LOx ligand functions as a bidentate chelate with a deprotonated phenolic oxygen atom and a nitrogen atom of an oxazolinyl ring.

引用

页码：251 / 254

页数：4

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