Photo/electroluminescent properties of novel bipolar oligomers

被引:12
作者
Kim, OK [1 ]
Woo, HY
Lee, KS
Kim, JK
Kim, DY
Shim, HK
Kim, CY
机构
[1] USN, Res Lab, Div Chem, Washington, DC 20375 USA
[2] Korea Adv Inst Sci & Technol, Dept Polymer Chem, Taejon 306010, South Korea
[3] Hannam Univ, Dept Macromol Sci, Taejon 300791, South Korea
[4] Korea Inst Sci & Technol, Polymer Mat Lab, Seoul 30650, South Korea
关键词
photoluminescence; electroluminescence and organic semiconductors;
D O I
10.1016/S0379-6779(00)00662-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Bipolar light-emitting (LE) oligomers consisting of three sequential segments centered by dithienothiophene (DTT) as pi -center and attached by D/D or D/A pair: D-pi -D (dye 1) or D-pi -A (dye 2) where D and A refer to hole transporting (HT) and electron-transporting (ET) units, respectively. Their redox properties are alike, suggesting the resemblance in bipolarity. Photoluminescence (PL) shows that the symmetric D/D system has a higher PL quantum efficiency relative to the D/A system. Electroluminescence (EL) from a single-layer device using a PVK blend displays a slightly higher light intensity with D/A system while EL quantum efficiency of D/D system doubles that of D/A system.
引用
收藏
页码:1607 / 1608
页数:2
相关论文
共 9 条
[1]  
De Jong F, 1971, J ORG CHEM, V36, P1645
[2]   New class of two-photon-absorbing chromophores based on dithienothiophene [J].
Kim, OK ;
Lee, KS ;
Woo, HY ;
Kim, KS ;
He, GS ;
Swiatkiewicz, J ;
Prasad, PN .
CHEMISTRY OF MATERIALS, 2000, 12 (02) :284-+
[3]   Solvatochromism of non-linear optical chromophores containing the dithienothiophene group in donor-acceptor molecules [J].
Kim, OK ;
Lehn, JM .
CHEMICAL PHYSICS LETTERS, 1996, 255 (1-3) :147-150
[4]  
KIM OK, 1999, J MATER CHEM, V9, P1476
[5]  
LEE JK, 1995, MACROMOLECULES, V28, P1174
[6]   Synthesis, properties, and application of new luminescent polymers with both hole and electron injection abilities for light-emitting devices [J].
Li, XC ;
Liu, YQ ;
Liu, MS ;
Jen, AKY .
CHEMISTRY OF MATERIALS, 1999, 11 (06) :1568-1575
[7]  
Peng ZH, 1998, ADV MATER, V10, P680, DOI 10.1002/(SICI)1521-4095(199806)10:9<680::AID-ADMA680>3.0.CO
[8]  
2-H
[9]   Highly efficient light-emitting polymers composed of both hole and electron affinity units in the conjugated main chain [J].
Song, SY ;
Jang, MS ;
Shim, HK ;
Hwang, DH ;
Zyung, T .
MACROMOLECULES, 1999, 32 (05) :1482-1487