A novel polyoxo(thio)molybdenum(V) sulfite compound:: Synthesis and crystal structure of {[Mo2V(μ-S)2O2]6(μ3-SO3)4(μ-SO3)12}20- anion

被引：21

作者：

Miras, HN

Woollins, JD

Slawin, AM

Raptis, R

Baran, P

Kabanos, TA ^{[1
]}

机构：

[1] Univ Ioannina, Dept Chem, Sect Inorgan & Analyt Chem, GR-45110 Ioannina, Greece

[2] Univ Puerto Rico, Dept Chem, Rio Piedras, PR 00931 USA

[3] Univ St Andrews, Dept Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

DALTON TRANSACTIONS | 2003年 / 19期

关键词：

D O I：

10.1039/b309473c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The non-cyclic polyoxo(thio) molybdate(V)-sulfite K-6(NH4)(14){[Mo-2(V)(mu-S)(2)O-2](6)(mu(3)-SO3)(4)(mu-SO3)(12)} . 7H(2)O 1 was prepared by self-condensation of [Mo-2(V)(mu-S)(2)O-2](2+) building block in the presence of (NH4)(2)SO3. Compound 1 was characterized by X-ray structure analysis as well as IR, UV-vis spectroscopies and thermogravimetric analysis.

引用

页码：3668 / 3670

页数：3

共 43 条

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