Dearomatization of benzene, deamidization of N,N-dimethylformamide, and a versatile new tungsten π base

被引：59

作者：

Graham, PM ^{[1
]}

Meiere, SH ^{[1
]}

Sabat, M ^{[1
]}

Harman, WD ^{[1
]}

机构：

[1] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 22期

关键词：

D O I：

10.1021/om030560h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first group VI eta(2)-coordinated benzene complex, TpW(NO)(PMe3)(eta(2)-benzene), is reported. The bound arene is activated toward Diels-Alder cyclo-addition, and substitution of the arene with DMF yields a rare example of a eta(2)-coordinated amide.

引用

页码：4364 / 4366

页数：3

共 19 条

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