Synthesis, crystal structure, and characterization of mixed-ligand complex of copper(I) with drug of norfloxacin and triphenyl phosphine:: [Cu(PPh3)2(H-Norf)]ClO4

被引：66

作者：

Chen, ZF

Li, BQ

Xie, YR

Xiong, RG ^{[1
]}

You, XZ

Feng, XL

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Zhongshan Univ, Anal Ctr, Guangzhou, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 07期

基金：

中国国家自然科学基金;

关键词：

crystal structure; norfloxacin; copper(I) complex; blue-fluorescent-emission; solvothermal synthesis;

D O I：

10.1016/S1387-7003(01)00207-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solvothermal reaction of norfloxacin (H-Norf) with [Cu(MeCN)(2)(PPh3)]. ClO4 yields a mixed-ligand complex [Cu(PPh3)(2)(H-Norf)]. ClO4 1 which is characterized by single crystal X-ray determination, IR, far-IR and solid state (PNMR)-P-31 as well as fluorescent spectrum. Crystallographic data for 1, C52H48ClCuFN3O7P2, triclinic P-1 (No. 2), a=10.0434(15), b = 13.5111 (17), c = 16.651 (2) Angstrom, alpha = 97.478 (2)degrees, beta = 93.610 (2)degrees, gamma = 115.928 (2)degrees. Fw = 1006.86, Z = 2, V = 2394.1 (5) Angstrom (3), R-1 = 0.0473, wR(2) = 0.1155, S = 0.735. (C) 2001 Published by Elsevier Science B.V.

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页码：346 / 349

页数：4

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