1H-NMR relaxation of water molecules in the aqueous microcrystalline cellulose suspension systems and their viscosity

An intensive study for aqueous microcrystalline cellulose (MCC) suspensions was carried out in view of the relationship between a viscosity and a H-1 spin-spin relaxation time (T-2) Of water, An investigation was carried out for four suspension systems with the different particle size distributions, The proton mole ratio (cr) of bound water against MCC particles and T-2 of bound water (T-2,T-b) were evaluated from the T-2 values obtained by Carr-Purcell-Meiboom-Gill (C.P.M.G) method and those by solid echo method, respectively, As a result of these analyses, the T-2,T-b value for the aqueous MCC suspension was evaluated as 5 x 10(-3) s and it was found that the system having a larger alpha tended to show a higher viscosity, By relating the above results to the observation of the suspensions by an optical microscope, it was concluded that a network formed by MCC particles plays an important role in generating a high viscosity of MCC suspension, and that an averaged mobility of water molecules is sensitively affected by the network structure.