Mechanochemical synthesis of Fe-S materials

被引：59

作者：

Jiang, JZ

Larsen, RK

Lin, R

Morup, S

Chorkendorff, I

Nielsen, K

Hansen, K

West, K

机构：

[1] Tech Univ Denmark, Dept Phys, DK-2800 Lyngby, Denmark

[2] Tech Univ Denmark, Dept Chem, DK-2800 Lyngby, Denmark

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1998年 / 138卷 / 01期

关键词：

mechanochemical reactions; iron sulfides; lithiation;

D O I：

10.1006/jssc.1998.7761

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Powder mixtures of metallic iron and sulfur have been milled in a high-energy planetary ball mill and the formation of iron sulfides has been studied by x-ray diffraction, Mossbauer spectroscopy, and scanning electron microscopy. For Fe:S ratios of 1:1 and 1:2 the final products are FeS with the modified NiAs structure and FeS2 (pyrite), respectively. No other iron sulfides were formed for any of the Fe:S ratios studied, The FeS phase has been tested as an electrode material in lithium batteries. (C) 1998 Academic Press.

引用

页码：114 / 125

页数：12

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