Multiferroic homochiral metal-organic framework

被引：101

作者：

Ye, Qiong ^{[1
]}

Fu, Da-Wei ^{[1
]}

Tian, Hang ^{[1
]}

Xiong, Ren-Gen ^{[1
]}

Chan, Philip Wai Hong ^{[2
]}

Huang, Songping D. ^{[3
]}

机构：

[1] SE Univ, Ordered Matter Sci Res Ctr, Nanjing 210096, Peoples R China

[2] Nanyang Technol Univ, Sch Math & Phys Sci, Div Chem & Biol Chem, Singapore 639798, Singapore

[3] Kent State Univ, Dept Chem, Kent, OH 44240 USA

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 03期

关键词：

D O I：

10.1021/ic701828w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reaction of (L)-ethyl lactate (Lig-Et) with Tb(CIO4)(3)center dot 6H(2)O gives colorless block (Lig)(2)Tb(H2O)(2)(CIO4) (1), in which 1 displays a laminar 2D framework. Ferroelectric and magnetic property measurements reveal that 1 probably is the first example of two "ferroic" metal-organic frameworks. Ferro-electricity of its analogue, (Lig)(2)Tb(D2O)(2)(CIO4) (2), further confirms the presence of the ferroelectric deuterium effect.

引用

页码：772 / 774

页数：3

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