A comment on the gurjar mechanism for alkene isomerization using the grubbs olefin metathesis catalysts

被引:34
作者
Edlin, CD
Faulkner, J
Fengas, D
Knight, CK
Parker, J
Preece, I
Quayle, P
Richards, SN
机构
[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
[2] GlaxoSmithKline Med Res Ctr, Stevenage SG1 2NY, Herts, England
[3] AstraZeneca Proc R&D, Avlon Works, Bristol BS10 7ZE, Avon, England
[4] Avecia, Manchester M9 8ZS, Lancs, England
关键词
Grubbs; atom transfer; isomerization; mechanism; allylic alcohol; metathesis;
D O I
10.1055/s-2005-862384
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The mechanism of allylic alcohol isomerization in the presence of the Grubbs metathesis catalysts is discussed.
引用
收藏
页码:572 / 576
页数:5
相关论文
共 82 条
[1]   Mechanistic studies of olefin metathesis by ruthenium carbene complexes using electrospray ionization tandem mass spectrometry [J].
Adlhart, C ;
Hinderling, C ;
Baumann, H ;
Chen, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (34) :8204-8214
[2]   Ruthenium-catalyzed chemoselective N-allyl cleavage: Novel Grubbs carbene mediated deprotection of allylic amines [J].
Alcaide, B ;
Almendros, P ;
Alonso, JM .
CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (23) :5793-5799
[3]   Non-metathetic behavior patterns of Grubbs' carbene [J].
Alcaide, B ;
Almendros, P .
CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (06) :1259-1262
[4]   Novel ruthenium-catalyzed cleavage of allyl protecting group in lactams [J].
Alcaide, B ;
Almendros, P ;
Alonso, JM .
TETRAHEDRON LETTERS, 2003, 44 (48) :8693-8695
[5]   A novel use of Grubbs' carbene. Application to the catalytic deprotection of tertiary allylamines [J].
Alcaide, B ;
Almendros, P ;
Alonso, JM ;
Aly, MF .
ORGANIC LETTERS, 2001, 3 (23) :3781-3784
[6]  
Ammar HB, 2002, J ORGANOMET CHEM, V662, P63
[7]   TRIMETHYLSILYLMETHYL AND OTHER ALKYLS OF CHROMIUM, MOLYBDENUM, RUTHENIUM, AND RHODIUM FROM INTERACTION OF MAGNESIUM DIALKYLS WITH METAL-METAL BONDED BINUCLEAR ACETATES OF CHROMIUM(II), MOLYBDENUM(II), RUTHENIUM(II,III), AND RHODIUM(II) [J].
ANDERSEN, RA ;
JONES, RA ;
WILKINSON, G .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1978, (05) :446-453
[8]   Selective isomerization of a terminal olefin catalyzed by a ruthenium complex: The synthesis of indoles through ring-closing metathesis [J].
Arisawa, M ;
Terada, Y ;
Nakagawa, M ;
Nishida, A .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, 41 (24) :4732-4734
[9]   Transition metal hydrides as active intermediates in hydrogen transfer reactions [J].
Bäckvall, JE .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 652 (1-2) :105-111
[10]   HOMOGENEOUS CATALYSIS - CATALYTIC PRODUCTION OF SIMPLE ENOLS [J].
BERGENS, SH ;
BOSNICH, B .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (03) :958-967